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Tsutsumi's group (Bio-functional polymer chemistry), Yamaguchi University

Japanese / English

Kazuhide Ueno (上野 和英)

Kazuhide Ueno, Ph.D.
Assistant Professor

Department of Applied Molecular Bioscience, Graduate School of Medicine
Department of Applied Chemistry, Faculty of Engineering
Yamaguchi University

2-16-1 Tokiwadai, Ube, Yamaguchi, 755-8611, Japan
Phone: +81-836-85-9285
FAX: +81-836-85-9201
E-mail: kzueno (at) yamaguchi-u.ac.jp


 Education Work experience Research topic Publications  Google Scholar

Education

 2006 (Apr) -2009 (Mar) Department of Chemistry and Biotechnology, Graduate School of Engineering, Yokohama National University, Ph. D. in Engineering (Prof. Masayoshi Watanabe)
 2004 (Apr) -2006 (Mar) Department of Chemistry and Biotechnology, Graduate School of Engineering, Yokohama National University, MEng
 2000 (Apr) -2004 (Mar) College of Engineering, Division of Materials Science and Chemical Engineering, Yokohama National University, BEng 
 1997 (Apr) -2000 (Mar) Kokura Highschool, Fukuoka 

Work experience

 2015 (Jan)- Assistant Professor, Department of Applied Molecular Bioscience, Graduate School of Medicine, Department of Applied Chemistry, Faculty of Engineering, Yamaguchi University
 2011 (Sep)
-2014 (Dec)
Postdoctoral Fellow, Department of Chemistry and Biotechnology, Yokohama National University (Prof. Masayoshi Watanabe)
 2009 (Sep)
-2011 (Aug)
Postdoctoral Research Associate, Department of Chemistry and Biochemistry, Arizona State University (Prof. C. Austen Angell)
 2009 (Mar) -2009 (Aug) Visiting Researcher, Institute of Multidisciplinary Research for Advanced Materials,
Tohoku University (Prof. Kazue Kurihara) 
 2008 (Apr)
-2010 (Mar)
 JSPS Research Fellow (DC2)

Research topics

  • Functional materials based on polymer gels and colloidal particles (2004~)
  • Fundamental study on colloid and surface chemistry in ionic liquids (2007~)
  • Fragility and transport properties of glass forming liquids (2009~)
  • Studies on solvate ionic liquids and highly concentrated electrolytes (2011~)
  • Novel organic and ionic liquid-based electrolytes for lithium secondary batteries (2009~)

Publications

Peer-reviewed Papers
 56 "Li+ solvation and ionic transport in lithium solvate ionic liquids diluted by molecular solvents"
Kazuhide Ueno, Junichi Murai, Kohei Ikeda, Seiji Tsuzuki, Mizuho Tsuchiya, Ryoichi Tatara, Toshihiko Mandai, Yasuhiro Umebayashi, Kaoru Dokko, Masayoshi Watanabe

J. Phys. Chem. C, ASAP (2015). DOI: 10.1021/acs.jpcc.5b11642
 55 "Thermosensitive soft glassy colloidal arrays of block copolymer grafted silica nanoparticlesin an ionic liquid"
Kazuhide Ueno, Toshimichi Fukai, Masayoshi Watanabe
Polymer Journal, ASAP (2015). DOI: 10.1038/pj.2015.105
 54 "Lithium-tin alloy/sulfur battery with a solvate ionic liquid electrolyte"
Kohei Ikeda, Shoshi Terada, Toshihiko Mandai, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
Electrochemistry, 83, 914-917 (2015).
 53 "Structural and aggregate analyses of (Li salt + glyme) mixtures: The complex nature of solvate ionic liquids"
Karina Shimizu, Adilson Freitas, Rob Atkin, Gregory Warr, Paul Anthony FitzGerald, Hiroyuki Doi, Soshi Saito, Yasuhiro Umebayashi, Masayoshi Watanabe, Kazuhide Ueno, José Nuno Canongia Lopes
Phys. Chem. Chem. Phys., 17, 22321-22335 (2015)
.
 52 "One-pot pyrolysis of lithium sulfate and graphene nanoplatelet aggregates: in situ formed Li2S/graphene composite for lithium–sulfur batteries"
Zhe Li, Shiguo Zhang, Ce Zhang, Kazuhide Ueno, Tomohiro Yasuda, Ryoichi Tatara, Kaoru Dokko, Masayoshi Watanabe
Nanoscale, 7, 14385-14392 (2015).
51 "One-step, template-free synthesis of highly porous nitrogen/sulfur-codoped carbons from a single protic salt and their application to CO2 capture"
Shiguo Zhang, Zhe Li, Kazuhide Ueno, Ryoichi Tatara, Kaoru Dokko and Masayoshi Watanabe
J. Mater. Chem. A, 3, 17849-17857 (2015)
50  "Adsorption of Polyether Block Copolymers at Silica–Water and Silica–Ethylammonium Nitrate Interfaces"
Zhengfei Chen, Yumi Kobayashi, Grant Bruce Webber, Kazuhide Ueno, Masayoshi Watanabe, Gregory G Warr, Rob Atkin
Langmuir, ASAP (2015).
49 "Recent advance in electrolytes for lithium-sulfur batteries"
Shiguo Zhang, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe

Adv. Energy. Mater., ASAP (2015).
(Review)
48 "Protic-salt-derived nitrogen/sulfur-codoped mesoporous carbon for the oxygen reduction reaction and supercapacitors"
Shiguo Zhang, Ai Ikoma, Kazuhide Ueno, Zhengjian Chen, Kaoru Dokko, Masayoshi Watanabe
ChemSusChem, 8, 1608-1617 (2015).
47 "Hydrogen-bonding supramolecular protic salt as an “all-in-one” precursor for nitrogen-doped mesoporous carbons for CO 2 adsorption" 
Shiguo Zhang, Toshihiko Mandai, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
Nano Energy, 13, 376-386 (2015).
46 "Micelle structure of novel diblock polyethers in water and two protic ionic liquids (EAN and PAN)"
Zhengfei Chen, Paul A FitzGerald, Yumi Kobayashi, Kazuhide Ueno, Masayoshi Watanabe, Gregory G Warr, Rob Atkin
Macromolecules, 48, 1843–1851 (2015). 
45 "Li+ solvation in glyme–Li salt solvate ionic liquids"
Kazuhide Ueno, Ryoichi Tatara, Seiji Tsuzuki, Soshi Saito, Hiroyuki Doi, Kazuki Yoshida, Toshihiko Mandai, Masaru Matsugami, Yasuhiro Umebayashi, Kaoru Dokko, Masayoshi Watanabe
Phys. Chem. Chem. Phys., 17, 8248-8257 (2015).
44 "Solvent activity in electrolyte solutions controls electrochemical reactions in Li-ion and Li-sulfur batteries"
Heejoon Moon, Toshihiko Mandai, Ryoichi Tatara, Kazuhide Ueno, Azusa Yamazaki, Kazuki Yoshida, Shiro Seki, Kaoru Dokko, Masayoshi Watanabe
J. Phys. Chem. C, 119, 3957–3970 (2015).
43 "Li+ ion transport in polymer electrolytes based on a glyme-Li salt solvate ionic liquid"
Ryosuke Kido, Kazuhide Ueno, Kaori Iwata, Yuzo Kitazawa, Satoru Imaizumi, Toshihiko Mandai, Kaoru Dokko, Masayoshi Watanabe
Electrochim. Acta, ASAP (2015).
42 "Effect of ionic size on solvate stability of glyme-based solvate ionic liquids"
Toshihiko Mandai, Kazuki Yoshida, Seiji Tsuzuki, Risa Nozawa, Hyuma Masu, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
J. Phys. Chem. B, 119, 1523–153 (2015).
41 "Pentaglyme-K salt binary mixtures: phase behavior, solvate structures, and physicochemical properties"
Toshihiko Mandai, Seiji Tsuzuki, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
Phys. Chem. Chem. Phys., 17, 2838-2849 (2015).
40 "Upper limit of nitrogen content in carbon materials"
Shiguo Zhang, Seiji Tsuzuki, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
Angew. Chem. Int. Ed., 54, 1302-1306 (2015).
39 "Structures of [Li(glyme)]+ complexes and their interactions with anions in equimolar mixtures of glymes and Li[TFSA]: analysis by molecular dynamics simulations"
Seiji Tsuzuki, Wataru Shinoda, Masaru Matsugami, Yasuhiro Umebayashi, Kazuhide Ueno, Toshihiko Mandai, Shiro Seki, Kaoru Dokko, Masayoshi Watanabe
Phys. Chem. Chem. Phys., 17, 126-129 (2015).
38 "Nanostructure of [Li(G4)] TFSI and [Li(G4)]NO3 solvate ionic liquids at HOPG and Au(111) electrode interfaces as a function of potential"
Ben McLean, Hua Li, Ryan Stefanovic, Ross J. Wood, Grant B. Webber, Kazuhide Ueno, Masayoshi Watanabe, Gregory G. Warr, Alister Page, Rob Atkin
Phys. Chem. Chem. Phys., 17, 325-333 (2015).
37 "Mechanism of Li ion desolvation at the interface of graphite electrode and glyme-Li salt solvate ionic liquids"
Heejoon Moon, Ryoichi Tatara, Toshihiko Mandai, Kazuhide Ueno, Kazuki Yoshida, Naoki Tachikawa, Tomohiro Yasuda, Kaoru Dokko, and Masayoshi Watanabe 
J. Phys. Chem. C118, 20246-20256 (2014).
36 "Gelation of solvate ionic liquid by self-assembly of block copolymer and characterization as polymer electrolyte"
Yuzo Kitazawa, Kaori Iwata, Satoru Imaizumi, Hyungmin Ahn, Sung Yeon Kim, Kazuhide Ueno, Moon Jeong Park, and Masayoshi Watanabe
Macromolecules, 47, 6009-6016 (2014).
35 "Chelate effects in glyme/lithium bis(trifluoromethanesulfonyl)amide solvate ionic liquids, part 2: importance of solvate-structure stability for electrolytes of lithium batteries" 
Ce Zhang, Azusa Yamazaki,  Junichi Murai, Jun-Woo Park, Toshihiko Mandai, Kazuhide Ueno, Kaoru Dokko, and Masayoshi Watanabe
J. Phys. Chem. C, 118, 17362–17373 (2014). 
34 "Physicochemical properties of pentaglyme-sodium bis(trifluoromethanesulfonyl)amide solvate ionic liquid" 
Shoshi Terada, Toshihiko Mandai, Risa Nozawa, Kazuki Yoshida, Kazuhide Ueno, Seiji Tsuzuki, Kaoru Dokko, Masayoshi Watanabe
Phys. Chem. Chem. Phys., 16, 11737-11746 (2014).
33 "Chelate effects in glyme/lithium bis(trifluoromethanesulfonyl)amide solvate ionic liquids, part 1: stability of solvate cations and correlation with electrolyte properties" 
Ce Zhang, Kazuhide Ueno, Azusa Yamazaki, Kazuki Yoshida, Toshihiko Mandai, Yasuhiro Umebayashi, Kaoru Dokko, and Masayoshi Watanabe
J. Phys. Chem. B, 118, 5144-5153 (2014).
32 "Enhanced performance of sulfone-based electrolytes at lithium ion battery electrodes, including the LiNi0.5Mn1.5O4 high voltage cathode" 
Leigang Xue, Kazuhide Ueno, Seung-Yul Lee, C. Austen Angell
J. Power Sources262, 132-128 (2014).
31 "Criteria for solvate ionic liquids"
Toshihiko Mandai, Kazuki Yoshida, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
Phys. Chem. Chem. Phys., 16, 8761-8772 (2014).
(Perspective article)
30 "Solubility of poly(methyl methacrylate) in ionic liquids in relation to solvent parameters"
Kazuhide Ueno, Toshimichi Fukai,Tomomi Nagatsuka, Tomohiro Yasuda, Masayoshi Watanabe
Langmuir,
30, 3228-3235 (2014).
 
29 "Phase diagrams and solvate structures of binary mixtures of glymes and Na salts"
Toshihiko Mandai, Risa Nozawa, Seiji Tsuzuki, Kazuki Yoshida, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
J. Phys. Chem. B117, 15072–15085 (2013).
 
28 "Ionic liquid electrolytes for lithium-sulfur batteries"
Jun-Woo Park, Kazuhide Ueno, Naoki Tachikawa, Kaoru Dokko, Masayoshi Watanabe
J. Phys. Chem. C117, 20531-20541 (2013).
27 "Anionic effects on solvate ionic liquid electrolytes in rechargeable lithium-sulfur batteries"
Kazuhide Ueno, Jun-Woo Park, Azusa Yamazaki, Toshihiko Mandai, Naoki Tachikawa, Kaoru Dokko, Masayoshi Watanabe
J. Phys. Chem. C117, 20509-20156 (2013).
26 "Solvate ionic liquid, [Li(triglyme)1][NTf2], as electrolyte for rechargeable Li/air battery: discharge depth and reversibility"

Ryoichi Tatara, Naoki Tachikawa, Hoi-Min Kwon, Kazuhide Ueno, Kaoru Dokko and Masayoshi Watanabe

Chem. Lett42, 1053-1055 (2013).
25 "EQCM Measurement of Deposition and Dissolution of Lithium in Glyme-Li Salt Molten Complex"

Nobuyuki Serizawa, Shiro Seki, Katsuhito Takei, Hajime Miyashiro, Kazuki Yoshida, Kazuhide Ueno, Naoki Tachikawa, Koru Dokko, Masayoshi Watanabe, Takashi Miura

J. Electrochem. Soc. 160, A1529-A1533 (2013).
24 "Solvate ionic liquid electrolyte for Li–S batteries"

Kaoru Dokko, Naoki Tachikawa, Kento Yamauchi, Mizuho Tsuchiya, Azusa Yamazaki, Eriko Takashima, Jun-Woo Park, Kazuhide Ueno, Shiro Seki, Nobuyuki Serizawa, and  Masayoshi Watanabe

J. Electrochem. Soc. 160, A1304-A1310 (2013).

23 "Solvent effect of room-temperature ionic liquids on electrochemical reactions in lithium–sulfur batteries"

Jun-Woo Park, Kento Yamauchi, Eriko Takashima, Naoki Tachikawa, Kazuhide Ueno, Kaoru Dokko, and Masayoshi Watanabe

J. Phys. Chem. C , 117, 4431-4440 (2013).
22 "Anhydrous superprotonic polymer by superacid protonation of crosslinked (PNCl2)n"
Younes Ansari, Kazuhide Ueno, Zuofeng Zhao, C. Austen Angell
J. Phys. Chem. C117, 1548-1553 (2013).
21 "Lithium salt solutions in mixed sulfone and sulfone-carbonate solvents: a Walden plot analysis of the maximally conductive compositions"
Seung-Yul Lee, Kazuhide Ueno, C. Austen Angell
J. Phys. Chem. C, 116, 23915-23920 (2012).
20 "Glyme-Li salt equimolar molten mixtures: concentrated solutions or solvate ionic liquids?"
Kazuhide Ueno, Kazuki Yoshida, Mizuho Tsuchiya, Naoki Tachikawa, Kaoru Dokko, Masayoshi Watanabe
J. Phys. Chem. B116, 11323-11331 (2012).
19  "Heat capacities and glass transitions of ion gels"
Osamu Yamamuro, Takenori Someya, Maiko Kohu, Takeshi Ueki, Kazuhide Ueno, Masayoshi Watanabe
J. Phys. Chem. B, 116, 10935-10940 (2012).
18 "Microscopic insight into ion gel dynamics using neutron spesctroscopy"
Maiko Kofu, Takenori Someya, Soichi Tatsumi, Kazuhide Ueno, Takeshi Ueki, Masayoshi Watanabe, Takuro Matsunaga, Mitsuhiro Shibayama, Victoria Garca-Sakai, Madhusudan Tyagi, Osamu Yamamuro
Soft Matter8, 3888-3897 (2012).
 
17  "Ionic liquids as oxidic media for electron transfer studies"
Kazuhide Ueno, C. Austen Angell
J. Chem. Phys., 136, 244501 (2012).
16 "Protic ionic liquids based on decahydroisoquinoline: lost superfragility and fragility-ionicity correlation"
Kazuhide Ueno, Zuofeng Zhao, Masayoshi Watanabe, C. Austen Angell
J. Phys. Chem. B, 116 , 63-70 (2012).
15 "On the decoupling of relaxation modes in a molecular liquid caused by isothermal introduction of 2 nm structural inhomogeneities"
Kazuhide Ueno, C. Austen Angell
J. Phys. Chem. B, 115 , 13994-13999 (2011).
14 "High conductivity, and ‘dry’ proton motion, in guanidinium salt melts and binary solutions"
Zuofeng Zhao, Kazuhide Ueno, C. Austen Angell
J. Phys. Chem. B, 115, 13467-13472 (2011).
13 "From colloidal stability in ionic liquid to advanced soft materials using the unique media"
Kazuhide Ueno, Masayoshi Watanabe
Langmuir, 27, 9105-9115 (2011).
(Invited feature article, Front cover)
12 "Thermosensitive, soft glassy and structural colored colloidal array in ionic liquid: colloidal glass to gel transition"
Kazuhide Ueno, Aya Inaba, Takeshi Ueki, Masashi Kondoh, Masayoshi Watanabe
Langmuir, 26, 18031-18038 (2010).
11 "Soft glassy colloidal arrays in an ionic liquid: colloidal glass transition, ionic transport, and structural color in relation to microstructure"
Kazuhide Ueno, Yuta Sano, Aya Inaba, Masashi Kondoh, Masayoshi Watanabe
J. Phys. Chem. B114, 13095-13103 (2010)
.
10 "Resonance shear measurement of nanoconfined ionic liquids"
Kazuhide Ueno, Motohiro Kasuya, Masayoshi Watanabe, Masashi Mizukami, Kazue Kurihara
Phys. Chem. Chem. Phys., 12, 4066-4071 (2010).
 
9 "Ionicity in ionic liquids: correlation with ionic structure and physicochemical properties"
Kazuhide Ueno, Hiroyuki Tokuda, Masayoshi Watanabe
Phys. Chem. Chem. Phys., 12, 1649-1658 (2010).(Perspective article, Inside front cover)
8 "Photoisomerization-induced tunable LCST phase separation of azobenzene-containing polymers in an ionic liquid"
Takeshi Ueki, Ayuko Yamaguchi, Naoki Ito, Koichi Kodama, Junji Sakamoto, Kazuhide Ueno, Hisashi Kokubo, Masayoshi Watanabe
Langmuir, 25, 8845-8848 (2009).
7 "Thermosensitive self-assembly of diblock copolymers with lower critical micellization temperatures in an ionic liquid"
Saki Tamura, Takeshi Ueki, Kazuhide Ueno, Koichi Kodama, Masayoshi Watanabe
Macromolecules, 42, 6239-6244 (2009). 
6 "Electrochromism based on structural colour changes in a polyelectrolyte gel"
Kazuhide Ueno, Junji Sakamoto, Yukikazu Takeoka, Masayoshi Watanabe
J. Mater. Chem., 19, 4778-4783 (2009).
5 "A soft glassy colloidal array in ionic liquid, which exhibits homogeneous, nonbrilliant, and angle-independent structural colours"
Kazuhide Ueno, Aya Inaba, Yuta Sano, Masashi Kondoh, Masayoshi Watanabe
Chem. Commun., 3603-3605 (2009).
4 "Colloidal interaction in ionic liquids: effects of ionic structures and surface chemistry on rheology of silica colloidal dispersions"
Kazuhide Ueno, Satoru Imaizumi, Kenji Hata, Masayoshi Watanabe
Langmuir, 25, 825-831 (2009). 
3 "Nanocomposite ion gels based on silica nanoparticles and an ionic liquid: ionic transport, viscoelastic properties, and microstructure"
Kazuhide Ueno, Kenji Hata, Toru Katakabe, Masashi Kondoh, Masayoshi Watanabe
J. Phys. Chem. B, 112, 9013-9019 (2008). 
2  "Colloidal stability of bare and polymer-grafted silica nanoparticles in ionic liquids"
Kazuhide Ueno, Aya Inaba, Masashi Kondoh, Masayoshi Watanabe
Langmuir, 24, 5253-5259 (2008).
1 "An electro- and thermochromic hydrogel as a full-color indicator"
Kazuhide Ueno, Kazuki Matsubara, Masayoshi Watanabe, Yukikazu Takeoka
Adv. Mater., 19, 2807-2812 (2007).


総説・解説・Proceedings

7 "Colloidal stability in ionic liquids and relevant soft materials"
Kazuhide Ueno, Masayoshi Watanabe
2012 MRS Spring Meeting Proceedings, 1473: mrss12-1473-bbb03-03 (2012).
6 "コロイド分散体としてのイオン液体"
上野和英、渡邉正義
Electrochemistry (電気化学および工業物理化学), 80(8), 596-601 (2012).
5 "イオン液体中のコロイド分散安定性"
上野和英、渡邉正義
Colloid and Interface Communication, 35(3), 9-11 (2011).
4 "Soft is strong"
C. Austen Angell, Kazuhide Ueno
Nature, 462, 45-46 (2009). (News&Views)
3 "化学レビュー15 材料化学ーイオン液体の魅力的な特性"
上野和英、渡邉正義
化学, 64, 48-52 (2009).
2 "Nanostructured colloidal arrays in an ionic liquid"
Kazuhide Ueno, Yuta Sano, Aya Inaba, Masayoshi Watanabe
高分子
, 58, 63 (2009). (Hot topics)
1 "構造色を変化させるエレクトロクロミックゲル"
上野和英、渡邉正義
高分子, 55, 934-937 (2006).


Book Capter

4 "Chapter 2 Physical Chemistry of Ionic Liquids, Inorganic and Organic, Protic and Aprotic"
C. Austen Angell, Xu Wu, Masahiro Yoshizawa, Akitoshi Hayashi, Jean-Philippe Belieres, Pierre Lucas, Marcelo Videa, Zuofeng Zhao, Kazuhide Ueno, Younes Ansari, Jeffery Thomson, Dominic Gervasio
Electrochemical Aspects of Ionic Liquids 2nd edition edited by H. Ohno, John Wiley & Sons, Inc., pp 5-31 (2011).
3 "8章 イオン液体中のコロイド粒子の自己集合" 
永塚智三、上野和英、渡邉正義
イオン液体III―ナノ・バイオサイエンスへの挑戦― 大野弘幸監修 (シーエムシー出版), pp 61-72 (2010).
2 "Chapter 14 Silica colloidal suspensions in ionic liquids: colloidal stability and fabrication of ion gels on the basis of colloidal self-assembly"
Kazuhide Ueno, Masayoshi Watanabe
ACS Symposium Series, Ionic Liquids: From Knowledge to Application, pp 199-210 (2010).
1 "4章 電解質材料, 4.4 イオン液体の基礎"
上野和英、渡邉正義
次世代自動車技術用リチウムイオン電池の材料開発 金村聖志監修 (シーエムシー出版), pp 132-148 (2008).


Hiromori Tsutsumi's Lab.
(Energy and Functional Materials)
Graduae School of Sciences and Technology for Innovation,
Faculty of Engineering, Applied Chemistry, Yamaguchi University

Faculty of Engineering Main Bulding Room 404 (Ube Campus)
2-16-1 Tokiwadai, Ube, Yamaguchi, Japan, 755-8611

TEL: +81-836-85-9282
FAX: +81-836-85-9201